The Vocabulary and Concepts of Organic Chemistry (Second Edition).pdf

THE VOCABULARY AND CONCEPTS

OF ORGANIC CHEMISTRY

THE VOCABULARY AND

CONCEPTS OF ORGANIC

CHEMISTRY

SECOND EDITION

Milton Orchin

Roger S. Macomber

Allan R. Pinhas

R. Marshall Wilson

A John Wiley & Sons, Inc., Publication

Published by John Wiley & Sons, Inc., Hoboken, New Jersey.

Published simultaneously in Canada.

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Library of Congress Cataloging-in-Publication Data is available.

ISBN 0-471-68028-1

Printed in the United States of America

10987654321

CONTENTS

1 Atomic Orbital Theory

2 Bonds Between Adjacent Atoms: Localized Bonding,

Molecular Orbital Theory

3 Delocalized (Multicenter) Bonding

4 Symmetry Operations, Symmetry Elements, and

Applications

5 Classes of Hydrocarbons

110

6 Functional Groups: Classes of Organic Compounds

139

7 Molecular Structure Isomers, Stereochemistry, and

Conformational Analysis

221

8 Synthetic Polymers

291

9 Organometallic Chemistry

343

10 Separation Techniques and Physical Properties

387

11 Fossil Fuels and Their Chemical Utilization

419

12 Thermodynamics, Acids and Bases, and Kinetics

450

13 Reactive Intermediates (Ions, Radicals, Radical Ions,

Electron-Deficient Species, Arynes)

505

14 Types of Organic Reaction Mechanisms

535

15 Nuclear Magnetic Resonance Spectroscopy

591

vi CONTENTS

16 Vibrational and Rotational Spectroscopy: Infrared, Microwave,

and Raman Spectra

657

17 Mass Spectrometry

703

18 Electronic Spectroscopy and Photochemistry

725

Name Index

833

Compound Index

837

General Index

849

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