Ir And Raman Spectroscopy - Wartewig.pdf

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Front Matter
Siegfried Wartewig
IR and Raman Spectroscopy
IR and Raman Spectroscopy: Fundamental Processing. Siegfried Wartewig
Copyright © 2003 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
ISBN 3-527-30245-X
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Spectroscopic Techniques:
An Interactive Course
Siegfried Wartewig
IR and Raman Spectroscopy
Fundamental Processing
2003, ISBN 3-527-30245-X
Christian Schorn
NMR Spectroscopy: Data Acquisition
2001, ISBN 3-527-28827-9
Peter Bigler
NMR Spectroscopy: Processing Strategies
Second Updated Edition
2000, ISBN 3-527-29990-4
Ursula Weber/Herbert Thiele
NMR Spectroscopy: Modern Spectral Analysis
1998, ISBN 3-527-28828-7
Erno Pretsch / Jean-Thomas Clerc
Spectra Interpretation of Organic Comp^nds \
1997, ISBN 3-527-28826-0
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Siegfried Wartewig
IR and Raman Spectroscopy
Fundamental Processing
WILEY-
VCH
WILEY-VCH GmbH & Co. KGaA
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Prof. Dr. Siegfried Wartewig
Institute of Applied Dermatopharmacy
Martin-Luther-University Halle-Wittenberg
Wolfgang-Langenbeck-Strasse 4
06120 Halle-Wittenberg
Germany
This book and CD-ROM were carefully produced. Nevertheless, editors, authors and publisher
do not warrant the information contained therein to be free of errors. Readers are advised to
keep in mind that statements, data, illustrations, procedural details or other items may inad-
vertently be inaccurate.
A CD-ROM containing a demo version of the program OPUS (© Bruker Optik GmbH, Rudolf-Plank-
Strasse 23, D-76275 Ettlingen, Germany) is enclosed.
Library of Congress Card No. applied for
A catalogue record for this book is available from the British Library.
Bibliographic information published by Die Deutsche Bibliothek
Die Deutsche Bibliothek lists this publication in the Deutsche Nationalbibliografie; detailed biblio-
graphic data is available in the Internet at http://dnb.ddb.de
© 2003 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
All rights reserved (including those of translation in other languages). No part of this book may be
reproduced in any form - by photoprinting, microfilm, or any other means - nor transmitted or trans-
lated into machine language without written permission from the publishers. Registered names, trade-
marks, etc. used in this book, even when not specifically marked as such, are not to be considered
unprotected by law.
Printed in the Federal Republic of Germany.
Printed ion acid-free paper.
Typesetting Hagedorn Kommunikation, Viernheim
Printing betz-druck gmbh, Darmstadt
ISBN 3-527-30245-X
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Contents
Preface IX
Acknowledgments X
1
Introduction 1
2
Your Personal "OPUS Workstation" 3
2.1
Technical Requirements 3
2.3
Starting OPUS 4
3
OPUS Basics 9
3.1
Loading and Selecting a File 10
3.2
The Browser Window 13
3.3
The Spectrum Window 15
3.5
Choosing a Spectral Range 22
3.6
The Toolbars 26
4
Basic Principles of Vibrational Spectroscopy 27
4.1
The Infrared Spectrum 29
4.3
The Raman Spectrum 30
5.1
Fourier Transform Technique 35
5.2
Advantages of Fourier Transform Spectroscopy 37
5.2.1
Connes Advantage 37
5.2.2
Jacquinot Advantage 40
5.2.3
Fellget Advantage 40
5.3
Discrete Fourier Transformation 40
5.3.1
Picket Fence Effect: Zerofilling 41
5.3.2
Aliasing 41
5.4
Effect of the Finite Record Length: Leakage and Apodization 42
5.5
Phase Correction 48
2.2
Installing OPUS 4
3.4
The Report Window 22
4.2
Molecular Vibrations 27
5
The Michelson Interferometer 35
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